Product ID:07906 FORMULATED ANTI-FREEZE 104, 1052103
MSDS Date:04/01/1987
FSC:6850
NIIN:00N049729
MSDS Number: BVDGZ

TEXACO INC

BEACON, NY 12508
US

Emergency Phone: 914-831-3400 EXT 406

Info Phone: 914-831-3400

Preparer: R.T. RICHARDS

Cage: 3B431

TEXACO PIPELINE INC (SUB OF TEXACO INC)

42286 HOUSTON, TX 77242-2286 US

Telephone: 713-953-4260

Cage: 3B431

ETHYLENE GLYCOL; (1,2-ETHANEDIOL)

CAS: 107-21-1

RTECS: KW2975000

Fraction By Weight: 100%

OSHA PEL 50 PPM, C

ACGIH TLV: 50 PPM, VAPOR, C

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

SODIUM BORATE, DECAHYDRATE; (BORAX)

CAS: 1303-96-4

RTECS: VZ2275000

Fraction By Weight: <4%

OSHA PEL 10 MG/M3

ACGIH TLV: 5 MG/M3

WASTE TREATMENT PLANTS & WOULD THEREFORE PRESENT NO

RTECS: 9999999ZZ

MAY RENDER THE RESULTING MATERIAL

RTECS: 9999999ZZ

HAZ IF USED TO STORE TOX, FLAMM/REACTIVE MATLS.

RTECS: 9999999ZZ

EXPLO/TOX FUMES FROM RESIDUES. DO NOT

RTECS: 9999999ZZ

SKIN AREAS SEVERAL TIMES DAILY W/SOAP & WATER

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50:(ORAL,RAT) 4.7-8.5 G/KG.
Routes of Entry: Inhalation:NO Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:EYES:BELIEVED TO CAUSE SLIGHT
IRRIT. SKIN:BELIEVED TO BE SLIGHTLY IRRITATING UPON PRLNG CONT.
INHAL:DROW, NARCOS & UNCON POSS UPON EXPOS TO HIGH CONCS IN POORLY
VENTILATED CONFINED SPACES. CHRON IC:LIVER & KIDNEY DMG IN 2 YR RAT
FEEDING STUDY USING 1-2% ETHYLENE GLYCOL. ORAL ADMIN OF VERY HIGH
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:DOSES OF ETHYLENE GLYCOL PRDCD BIRTH
DEFECTS IN LAB ANIMALS. SYMPS OF INGEST:BEHAVIORAL CHANGES, DROW,
VOMIT, DIARR, THIRST, CONVLS, CYANOSIS, RAPID HEART RATE, PULM
EDEMA & RENAL FAILURE. AC UTE/CHRONIC ORAL COMSUMPTION FOR PRODS
CNTNG ETHYLENE GLYCOL CAN PRDCE ADVERSE HLTH EFTS IN HUMANS. SUCH
PRODS (SUPDAT)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR AT LST 15 MINS. SKIN:WASH EXPOS AREAS
W/SOAP & WATER. INGEST:GIVE LG QTYS OF WATER, THEN INDUCE VOMIT
IMMED. GET IMMED MED ATTN. DO NOT MAKE UNCONSCIOUS PERSON VOMIT.
NEVER GIVE ANYTHING BY MOUTH TO UNCONSCIOUS PERSON. INHAL:REMOVE
TO FRESH AIR; IF NOT BRTHG APPLY ARTF RESP. GET MED ATTN. KEEP
AFFECTED PERSON WARM & AT REST.

Lower Limits:3.2%
Extinguishing Media:ACCORDING TO NFPA GUIDE, USE WATER SPRAY, DRY
CHEMICAL, FOAM OR CARBON DIOXIDE.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP .
WATER/FOAM MAY CAUSE FROTHING. USE WATER TO COOL FIRE-EXPOS CNTNRS.
IF LEAK/SPILL HAS NOT IGNITED, (SUPDAT)
Unusual Fire/Explosion Hazard:NONE.

Spill Release Procedures:AVOID CONTACT W/EYES. CONTAIN SPILL IF
POSSIBLE. WIPE UP OR ABSORB ON SUITABLE MATL & SHOVEL UP.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:WARNING! HARMFUL/FATAL IF SWALLOWED.
KEEP OUT OF REACH OF CHILDREN. MAY CAUSE IRRIT TO EYES. DO NOT
DRINK ANTIFREEZE/SOLN. AVOID CONT W/EYES.
Other Precautions:DO NOT STORE IN OPEN/UNLABELED CNTNRS. MIN FEASIBLE
HNDLG TEMPS SHOULD BE MAINTAINED. PERIODS OF EXPOS TO HIGH TEMPS
SHOULD BE MINIMIZED. WATER CONTAM SHOULD BE AVOIDED. CAUTION:MISUSE
OF EMPTY CNTNRS CAN BE HAZ. EMPTY CNTNRS CAN BE (ING 5)

Respiratory Protection:NIOSH/MSHA APPROVED SUPPLIED AIR
POSITIVE-PRESSURE FULL-FACEPIECE RESPIRATORS IN EMERGENCIES,
CLEANING SPILLS, ENTRY INTO TANKS, CONFINED SPACES.
Ventilation:VENTILATION ADEQUATE TO MEET COMPONENT PERMISSIBLE
CONCENTRATIONS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEMICAL TYPE GOGGLES & FACE SHIELD.
Other Protective Equipment:NONE SPECIFIED BY MANUFACTURER.
Work Hygienic Practices:WASH THORO AFTER HNDLG. EXPOS EMPLOYEES SHOULD
EXERCISE REAS PERSONAL CLEANLINESS, THIS INCLS CLEANSING EXPOS (ING
7)
Supplemental Safety and Health
FIRE FIGHT PROC:USE WATER SPRAY TO DISPERSE VAPS & TO PROVIDE PROT FOR
PERS ATTEMPTING TO STOP LEAK. EFTS OF OVEREXP:SHOULD NOT BE USED IN
POTABLE WATER SYS/OTHER SYS WHERE CONTAM OF POTABLE WATER SUP PLIES
IS POSS. THIS PROD, WHEN INTRODUCED INTO WATER SYS WILL BE DEGRADED
BIOLOGICALLY IN BOTH SURF WATERS & (ING 3)

Boiling Pt:B.P. Text:388F,198C
Vapor Pres:<0.1
Vapor Density:2.14
Spec Gravity:1.13
pH:10.8
Evaporation Rate & Reference:<1
Solubility in Water:SOLUBLE
Appearance and Odor:FLUORESCENT GREEN LIQUID; MILD ODOR.
Percent Volatiles by Volume:NIL

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS.
Stability Condition to Avoid:NOT PROVIDED.
Hazardous Decomposition Products:CARBON MONOXIDE & CARBON DIOXIDE MAY
BE FORMED NO BURNING IN LIMITED AIR SUPPLY.

Waste Disposal Methods:DISP MUST BE I/A/W FED, STATE & LOC REGS . UNDER
RCRA, IT IS RESPONSIBILITY OF USER OF PRODS TO DETERMINE, AT TIME
OF DISP, WHETHER PROD MEETS RCRA CRITERIA FOR HAZ WASTE. THIS IS
BECAUSE PROD U SES, TRANSFORMATIONS, MIXT, PROCESSES, ETC (ING 4)

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